We look ahead to this UEFA Champions League match at Stadio Diego Armando Maradona with our Napoli vs Arsenal prediction and preview. After stumbling at the final hurdle in last season’s final, can the Gunners make a strong start to their latest European campaign?
Napoli vs Arsenal: The Key Stats
The Opta supercomputer saw Arsenal defeat Napoli in 52.3% of its pre-match simulations. Napoli have only lost three of their 13 home games against English clubs in major European competitions – but did lose their most recent such outing, against Chelsea (3–2) in the league phase of last season’s Champions League. Arsenal were the only team not to lose a single match in normal time in the entire 2025-26 Champions League campaign.Matchday 1 of the new Champions League campaign continues as the 2025-26 runners-up enter the fray, with Arsenal set for a trip to Napoli as they attempt to go one better than last season. They lost on penalties in the final against back-to-back winners PSG.
Napoli proved to be the worst of a bad bunch for Serie A in last season’s competition, failing to even get out of the 36-team league phase. They took just eight points from their eight matches, and lost four times, including defeats to both Manchester City and Chelsea.
Neither Inter, Juventus nor Atalanta made it beyond the round of 16 last term, but Napoli will be keen to buck that trend this time around.
However, despite winning their opening league game of the season, Massimiliano Allegri’s side have already hit a wall after back-to-back defeats to Como and Inter. They surrendered a 2–0 lead against the latter after Kai Havertz and Alessandro Buongiorno, with talismanic midfielder
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