The Addicks, who won the FA Cup back in 2004/05, have put their promotion charge to one side for the visit of the top-flight outfit.
Watch Charlton Athletic v Liverpool live on TNT Sports via HBO Max on Amazon Prime Video and Sky SportsThe Reds smashed London Bees 6-0 in the fourth round before beating Merseyside rivals Everton to set up their quarter-final at the Valley, which is set for its biggest attendance at a women's game in more than 20 years.
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Charlton Athletic v Liverpool kick-off time
What TV channel is Charlton Athletic v Liverpool on?
The game will be shown live on TNT Sports 1.
You can also access TNT Sports via HBO Max and stream directly to your smart TV.
Check out the latest deals for TNT SportsRegular subscribers can also stream matches on a variety of devices including laptops, smartphones and tablets via the HBO Max app.
Watch Charlton Athletic v Liverpool live on TNT Sports via HBO Max on Amazon Prime Video and Sky Sports
Is Charlton Athletic v Liverpool on radio?
Unfortunately this match will not be aired on national radio. Check your local BBC radio station for more information.
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Charlton Athletic v Liverpool odds
In working partnership with the Radio Times, bet365 has provided the following betting odds for this event:
bet365 odds: Charlton Athletic (TBC) Draw (TBC) Liverpool (TBC)*
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