Thousands of faithful gathered in St. Peter’s Square waited for smoke to pour from the flue on the chapel’s roof, which it did shortly before noon (1000 GMT).
They burn the ballot papers and mix them with chemicals to show how proceedings are going -- black signalling no pope and white announcing a new pontiff.
The red-hatted “princes of the Church” will keep on voting up to four times a day until someone wins a two-thirds majority.
Francis, the first pope from Latin America, was elected on the evening of the second day of the last conclave, held in 2013, as was his predecessor, Benedict XVI, in 2005.
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