Synthesis of a near-infrared light absorbing macrocyclic aromatic compound ...Middle East

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Synthesis of a near-infrared light absorbing macrocyclic aromatic compound
A ring-expanded porphyrin with no meso-bridges comprised of an odd number of pyrroles was successfully synthesized via the oxidative coupling of the corresponding terpyrrole. This porphyrin showed a 34pi aromatic character and an intense absorption at the near-infrared region. We analyzed the optical and electronic structures using magnetic circular dichroism spectroscopy and time-dependent density functional theory calculations.

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