Evolutional history of metal chalcogenide supertetrahedral clusters ...Middle East

Metal chalcogenide supertetrahedral clusters (MCSCs) are of significance for developing crystalline porous framework materials and atomically precise cluster chemistry. Early research focused on the synthetic and structural chemistry of MCSC-based porous semiconductor materials and their applications. Recently, focus has shifted to establish the atomically precise structure-composition-property relationship of MCSCs. This review covers three decades of e?orts on MCSCs, an outlook on remaining problems to be solved and future trends is also presented.

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