William made a surprise appearance on the chat show to talk about the Earthshot Prize, which he set up in 2020, and has five goals which an award is given - Protect and Restore Nature, Clean Our Air, Revive Our Oceans, Build a Waste-Free World and Fix Our Climate.
Norton and the Prince discussed the need to pair optimism and urgency when tackling climate change, while the guests also spoke about William's support for Aston Villa and his love of Christopher Nolan's films.
Last year's winners were announced at a ceremony in Rio de Janeiro, with attendees including Kylie Minogue, Shawn Mendes, then-Prime Minister Keir Starmer, then-Energy Secretary Ed Miliband and London Mayor Sadiq Khan.
On the show, William said: "For many years I was hearing stories about environment issues and one thing that struck me was the negativity and doom which got me down.
Next week's guests on The Graham Norton Show are set to include Michael Douglas, Glenn Close, Kieran Culkin, Naomi Ackie and the Sugababes - barring any more surprise royal appearances.
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