The Reds are one of nine teams that have made a perfect start to the League Phase campaign and currently occupy one of the top eight spots, which offer passage straight to the last 16.
Tuesday's game sees Andoni Iraola cross paths with close friend and former assistant coach Iñigo Pérez, who served under him at Rayo Vallecano and took charge at Villarreal in the summer.
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Liverpool v Villarreal kick-off time
What TV channel is Liverpool v Villarreal on?
You can tune in to watch the game live on Amazon Prime Video.
If you do decide to sign up, Amazon offers a 30-day free trial. Afterwards, a subscription costs £8.99 a month – or £95 per year – and offers free next day delivery on thousands of items, as well as the Amazon Prime Video library.
A host of smart TVs will come equipped with the Amazon Prime Video app, while you can also go via devices such as the Amazon Fire TV Stick or Google Chromecast.
Is Liverpool v Villarreal on radio?
Unfortunately, this match will not be aired on national radio but there will be regular updates on BBC Radio 5 Live.
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Liverpool v Villarreal odds
In working partnership with the Radio Times, bet365 has provided the following betting odds for this event:
bet365 odds: Liverpool (1/2) Draw (7/2) Villarreal (5/1)*
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*Odds subject to change. 18+. T&Cs apply. GambleAware.org. Note – The bonus code RT365 does not change the offer amount in any way.
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