SMBs are a form of ultrafast-charging, stable batteries that scientists say could one day be a cheap alternative to today's lithium-ion (Li-ion) batteries, which rely on geographically concentrated metals and easily catch fire. SMBs also differ from sodium-ion (Na-ion) batteries in that they use a metallic sodium anode rather than a graphite or hard carbon anode.
Dendrite formation is especially common in sodium batteries because sodium is a highly reactive metal. When charge runs through a Li-ion, Na-ion, or sodium metal battery, the anode always reacts with the electrolyte to form an oxide layer known as the SEI. This is typically 10 to 50 nanometers thick — about as wide as a small virus — but generally harmless. But with sodium, the SEI often cracks, forming bumps that attract sodium ions, which pile into dendrites.
To confirm the longevity of this approach, the scientists charged and discharged the battery for over 6,000 hours without dendrites short-circuiting the battery. They also noted that when they charged the battery from zero to 100% capacity in just four minutes, it retained electrical charge, measured in milliampere-hours per gram (mAh g–1), of 80.1. This is the equivalent of around half that retained in Li-ion batteries.
This is notable because the scientists achieved this in the new battery while still charging it quicker than Li-ion batteries can be charged. This is relevant because charging speed remains a sticking point for battery deployment in electric vehicles (EVs). The fastest charging EV today is the BYD Denza, which the Chinese automaker says can go from 10-70% in just five minutes. But this requires highly specialised, 1MW proprietary chargers.
Indeed, most batteries used for modern technologies, such as smartphones and EVs, are Li-ion. However, Li-ion batteries are expensive to produce because they contain the hard-to-obtain metals lithium and cobalt, and they are prone to catching fire.
SMBs are the focus of intense research because they theoretically combine the best of both types of batteries. Because SMBs use a sodium anode, rather Na-ion batteries that use graphite or hard carbon anode, they are lighter and cheaper to produce and therefore much more comparable to Li-ion in terms of size and weight. They are also safer because they operate using sodium ions, which are bulky and cannot flow to breaches in a battery wall fast enough to cause thermal runaway. This is the self-sustaining chain reaction that causes batteries to ignite when damaged.
Related storiesIf the issues of dendrite formation and stability at lower temperatures can be resolved, replicated and scaled, SMBs could reshape the economics of battery deployment over the next decade, the scientists said.
That's because devices like smartphones are subject to harsh temperature changes that affect the internal chemistry of batteries that rely on gel electrolytes. The research must first be replicated before manufacturers feel comfortable using pure sodium metal in place of well-understood graphite configurations.
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