The Gunners have had to do things the hard way in their European title defence – finishing outside the top four in the League Phase and beating OH Leuven 7-1 on aggregate in the play-off round.
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Chelsea are chasing a first Champions League triumph as they bid to follow up the domestic treble that they won in Sonia Bompastor's debut season.
They're unbeaten in the Champions League and qualified directly for the quarter-finals by finishing third in the League Phase table.
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Check out our live football on TV guide for the latest times and information.
Arsenal v Chelsea kick-off time
Benfica v Arsenal will kick off at 8pm.
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How to live stream Arsenal v Chelsea online
A host of smart TVs will come equipped with the app, while you can also go via devices such as the Google Chromecast.
Is Arsenal v Chelsea on radio?
You can listen to the match on BBC Radio 5 Live.
BBC Radio 5 Live is available on DAB radio, MW 693 kHz, 909 kHz and 990 kHz, or you can tune into the station via most TV packages. You can also listen to Radio 5 Live online via the BBC website or BBC Sounds app.
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Arsenal v Chelsea odds
In working partnership with the Radio Times, bet365 has provided the following betting odds for this event:
bet365 odds: Arsenal (11/10) Draw (13/5) Chelsea (21/10)*
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*Odds subject to change. 18+. T&Cs apply. GambleAware.org. Note – The bonus code RT365 does not change the offer amount in any way.
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