The former Manchester City and England goalkeeper picked out Rice for special praise on Match of the Day, alongside Gabby Logan and former Lionesses star Ellen White.
He said: "Up until this game, 97 per cent of [Arsenal's] corners this season have been direct, they've been slinging it into the box, they've been getting all set up and they've been looking dangerous.
"Like I said, 97 per cent [of Arsenal corners have been direct], the instruction from the side is set up and get that ball into some dangerous areas, but Declan Rice has gone: 'You know what, I can see Newcastle are napping, they've got used to the fact we're slinging balls in and can set up against it.' And he's locked eyes with Eberechi Eze.
"Declan Rice, beautiful ball in, and Merino, that is a sensational header. Honestly, I can't stress how delicate that is. Absolutely perfect in the corner."
Hart said: "That is an Arsenal player saying no, 1-1 is not enough. Get up the other end, get the ball back, it's show time. Little glance at the dugout to say sorry I took the short corner but deal with it, let's get back in this game."
Hart added: "Here we go, this is the Arsenal we expect. Bodies everywhere, Saliba lurking, Gabriel one-on-one with Dan Burn, he's saying get it into that near-post area, I'm going to make something happen."
The Gunners take on Olympiacos in the Champions League at the Emirates Stadium this week, before returning to their home patch for a clash against West Ham under new boss Nuno Espirito Santo.
Another last-gasp defeat at St James' Park, following Liverpool's smash-and-grab winner in August, leaves Eddie Howe's Newcastle in 15th place with just one victory in their opening six matches.
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